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IE3: Feed of liquids
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Hazards:
Chargeable liquid charges as it is agitated during the filling process. If
it comes into close proximity to a conductive earthed object, a discharge can
ignite an explosive atmosphere.
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Protective measures:
Feed the conductive paint before adding the solvent when adjusting the
viscosity.
Reduce the agitation speed when using non-conductive coating systems.
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When coating materials are being mixed and adjusted, a liquid of low
conductivity can become charged. There is a fundamental possibility of liquids
becoming charged during agitation procedures, even in the case of liquids of
moderate conductivity, though this material group can be regarded as of
secondary importance in the context of liquid coating applications because of
the low agitation speeds and the vessel geometry in the case of earthed
vessels. An ignition-capable charge accumulation is unlikely for materials of
moderate conductivity because of the negligible surface areas and the proximity
to the earthed vessel wall.
| Low conductivity |
|
κ ≤ 5 * 10-11 S/mc |
| Moderate conductivity |
5 * 10-11 S/m < |
κ ≤ 10 -9 S/m |
| High conductivity |
10 -9 S/m < |
κ |
Table: Classification of liquids by their conductivity
Coating systems are not generally classified as liquids of low
conductivity.
When adjusting the viscosity, on the other hand, aromatic compounds such as
xylene or toluene, which have a low viscosity, are also used. In such cases,
the conductive coating component must always be fed first when mixing. Where
the coating system is also based on aromatic solvents, supplementary measures,
such as reducing the agitation speed, may also have to be taken.
Table: Organic solvents of low conductivity
| Solvent name |
Conductivity range [S/m] |
| Paraffins |
10-14 to 10-11 |
| Aromatic compounds (e.g. toluene, xylene) |
10-13 to 10-11 |
| Kerosene |
10-13 to 5*10-11 |
| Gasolines (depending on sulphur content) |
10-13 to 10-10 |
| White oils |
10-13 to 10-10 |
| Ether |
10-13 to 10-10 |
| Aromatic solvent mixtures |
10-12 to 10-9 |
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